Sensitization is common in austentic stainless steels following welding or after prolonged exposure to service. An electrochemical study on stress corrosion cracking of. Stressed sensitized 304, 316, and 321 stainless steels were selected and subjected to various environments that. Alloy 347 stainless steel plate resists polythionic acid stress corrosion cracking in hydrocarbon service. While the lowcycle fatigue performance of metals is significantly influenced by corrosion, the corrosion damages and therefore the fatigue mechanisms.
Chloride stress corrosion cracking of an austenitic. Among them, the scc due to polythionic acid h 2sxo 6, x 3 6 is one of the most serious corrosion issue affecting equipment for hydrotreater and hydrocracker in complex refinery. Development of fitforpurpose austenitic stainless steels. Development of fitforpurpose austenitic stainless steels with. A thermal stabilization treatment at 899 900 deg c for two hours is specified for increasing the corrosion resistance to intergranular corrosion and polythionic acid stress corrosion cracking. This standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from polythionic acid pta stress corrosion cracking scc that can occur during a shutdown of refinery equipment. Soda ash washing can be a costly and time consuming endeavor for the refiner. Alloy 347 stainless steel plate does not perform well in chloride solutions, even in small concentrations, or in sulfuric acid. Sem fractograph of intergranular scc of type 316 stainless steel in polythionic acid showing brittle features. Standard recommended practice austenitic stainless steels.
The piping is currently constructed of 316l tubing. This paper will describe the details of polythionic acid. An austenitic stainless steel for sulfuric acid corrosion environments. Carbon steel and type 304 stainless steel samples were exposed in thirteen corrosion tests conducted in solutions with varying ph, oxygen content, so2 content and chloride ion content in a simulated sour water solution produced in the laboratory.
Stress corrosion cracking investigations on ubend samples of sensitized 304 austenitic stainless steel have been conducted in sulfurous acid solutions in the concentration range, 0. The astm standard for a376 and a 312 gives this treatment for the stabilzed grade austenitic stainless steels as a supplementary requirement without. Cracking is due to sulfur acids forming from sulfide scale, air and moisture acting on sensitized austenitic stainless steels. Alloy 347347h heat resistant stainless steel plate. Polythionic acid is formed in the presence of sulfur. What are the industrial practices being followed in. Ae monitoring from various types of stress corrosion cracking scc has been conducted for the past 15 years in our laboratory.
Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Stress corrosion cracking susceptibility of stainless. Pta stress corrosion cracking, and embrittlement of lowalloy steels. This theory implies that if surface energy is reduced, then. Corrosion rates were calculated, and ubends were examined for stress corrosion cracking. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. Polythionic acid corrosion in refinery hydroprocessors. In this chapter, the conditions for the occurrence of scc are first introduced. Nace sp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment, nace international, houston, tx. Sp01702018 protection of austenitic stainless steels. Stress corrosion cracking susceptibility of stainless steels and. In the process units with polythionic acid stress corrosion cracking ptascc such as hydrotreater or hydrocracker, the neutralization treatment like soda ash washing andor pwht, post weld heat treatment, are conducted for stabilized austenitic stainless steels of tp321h or tp347h to mitigate the potential of ptascc.
Other forms of scc in stainless steels include caustic cracking and polythionic acid scc. Ra20 is an austenitic stainless steel developed by carpenter technology corporation for the handling of dilute sulfuric and other reducing acid solutions. A shutdown includes the actual down time period and the contiguous periods required to shut down and start up the equipment. Stress corrosion cracking scc of duplex stainless steel. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. The purpose of this booklet, therefore, is to help materials engineers identify those applications and to provide data to support the use of stainless steels in the hightemperature, corrosive environments that may be encountered. Resistance to corrosion stainless steel tubing manufacturer. These characteristics are consistent with stress corrosion cracking due to polythionic acids. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. It can also be utilized in chloride or fluoride free caustic solutions at moderate temperatures.
In certain process units, such as hydrocracking, soda ash washing neutralization of austenitic stainless steel is required during turnarounds to mitigate the potential for polythionic acid stress corrosion cracking pta scc. The most commonly available duplex in north america is 2205, at a cost roughly 20% above that of 316l. Protection of austenitic stainless steel from polythionic acid stress. Lower sscc resistance of the pinhole prenotched specimen was observed. Stress corrosion cracking of sensitized 304 austenitic. Based on this analysis the leaks were caused by cracks that initiated on the id surface. The cracks are intergranular and narrow with no significant branching. This standard recommended practice provides methods to protect austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking pta scc occurring during downtimes and contiguous shutdown and startup periods. Stress corrosion cracking of gas pipelines 3 minute 2014 thesis. They can be subject to polythionic acid stress corrosion cracking during shut down.
Developed as a material to resist corrosion attack in phosphoric acid processing, the grades chemical composition ensures superior performance in a wide range of demanding conditions. Polythionic acids form from sulfide scales exposed to oxygen and water in the stainless steel that are sensitized which can occur in most stainless steel tube materials after exposures to temperatures in excess of 700f to. This paper discusses ae results of activepath dissolutiontype scc of austenitic stainless steel in chloride solution and fused salt, fluoride and polythionic acid solutions, brass. This standard is directed toward preventing stress corrosion.
Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Alloy for resistance to polythionic acid stress corrosion. Exposure to oxygen and water during turnaround forms polythionic acid and that leads to pta scc on sensitized stainless steel, where soda ash washing, nitrogen purge and pwht is required as a nace countermeasure. Various separations downstream remove the acid gases, particulate matter. Polythionic acid is another environment, which causes scc in. Stress corrosion cracking by krittin rattakham youtube. Resistant to chloride and polythionic acid stress corrosion cracking.
We have experienced repeated failures on seal flush piping on the naphtha and distillate reflux pumps in our crude fractionation unit. It appears that stress corrosion cracking in austenitic stainless steels in the. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Exploring factors controlling precorrosion fatigue of. The cast stainless generally did not polythionic crack but, the ferrite content were susceptible to sigma phase embrittlement. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. Cracking of sensitized stainless steels inspectioneering. Corrosion behaviour of stainless steel in organic acid solution. Failure analysis of impeller made of fv520b martensitic precipitated hardening stainless steel. Stress cracking agents in process streams are not the only cause of scc. Introduction the 304 stainless steel charge heater coil of a naphtha hydrotreater unit nht was found to be extensively cracked following unit shutdown, when soda ash washing was applied. The applications for stainless steels in petroleum refining are many and varied. The stress corrosion cracking sco of sensitized type 304 stainless steel. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing.
Polythionic stress corrosion cracking of stainless steel tube. Chemical studies of polythionic acid stresscorrosion cracking. Austenitic stainless steels are widely used in hydroprocessing units. In the process units with polythionic acid stress corrosion cracking ptascc. If the austenitic stainless steel tubes have become sensitised and need to be mechanically pigged to remove coke andor internal sulphide scale, they should be washed with soda ash solution first. Examples of polythionic acid scc pascc in a sensitized austenitic stainless steel and caustic scc in carbon steel equipment are presented. Alloy for resistance to polythionic acid stress corrosion cracking for. The test solution was prepared by passing sulfur dioxide gas into deionized water for 4 hours and then bubbling hydrogen sulfide for 3 hours. In each failure analysis case study, the cracking is characterized using various metallurgical laboratory techniques, including metallography and fractography, in order to identify the mode of failure. The ptascc of stainless steels is generally caused by.
Duplex stainless steel is a practical solution to most 304l or 316l scc failures. The alloy exhibits high resistance to chloride stress corrosion cracking, and to polythionic acid stress corrosion cracking. Electrochemical characteristics of polythionic acid stress corrosion cracking have been examined mainly on sensitized type 304 stainless steel. The most common fluid that causes inter granular stress corrosion cracking igscc in petrochemical plants and refineries is polythionic acid. Nace sp0170 protection of austenitic stainless steels. Experience with polythionic acid stress corrosion cracking. This acidic condition, along with temperatures high enough to sensitize stainless steel, often led to polythionic acid stress corrosion cracking of the valve bodies. Abstractlow temperature stress corrosion cracking of sensitized stainless steel, promoted by aqueous solutions of polythionates sxo, and related sulfur compounds. Penn stainless inventory now includes alloy 321 uns s32100 in sheet, sheet coil, plate, round bar, processed flat bar and tubular products. Pdf stress corrosion cracking damages researchgate.
Pdf polythionic acid corrosion in refinery hydroprocessors. The cracking was found when rust stainingleaks were observed. Stress corrosion cracking in stainless s teel question. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Polythionic acid stress corrosion cracking occurs on sensitized stainless heater tubes in hydroprocessing units. Stress corrosion cracking of sensitized austenitic. Refer also to nace rp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking. Stress corrosion cracking issues in syngas plants that may. Igscc is most common in sensitized 300 series stainless steel and higher nickel base austenitic alloys. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur.
All of the cracks observed were found underneath the coke deposits. Samans, stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution, corrosion. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. The alloys 321 and 347 are particularly useful under conditions which cause polythionic acid stress corrosion of nonstabilized austenitic stainless steel, such as alloy 304.
Exposure of nonstabilized austenitic stainless steel pipe to temperatures in the sensitizing range will cause the precipitation of chromium carbides at grain boundaries. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment this standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from pta scc that can occur during a shutdown of refinery equipment. The purpose of this paper is to investigate stress corrosion cracking scc for 304, 316, and 321 stainless steels in petroleum. Caustic may crack carbon as well as stainless steel. Polythionic acid stress corrosion cracking deterioration. Please let us know here why this post is inappropriate. Pascc occurs when sensitized stainless steels that have been in service. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Exposure of the austenitic stainless steel piping or equipment to moisture and air can lead to a potential for this type of cracking if the ss is sensitized.
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